18-冠醚-6,18-Crown-6;suitable for ion chromatography, ≥99.0% (GC)

别名:18-冠-6-醚;18冠醚6;十八冠醚-6;1,4,7,10,13,16-六氧环十八烷;Crown ether/18-Crown-6, 1,4,7,10,13,16-Hexaoxacyclooctadecane, 18-Crown-6

Empirical Formula (Hill Notation): C12H24O6 CAS号: 17455-13-9 分子量: 264.32 Beilstein: 1619616 EC 号: 241-473-5 MDL编号: MFCD00005113
货号(SKU): 80833
CAS号: 17455-13-9
MDL号: MFCD00005113
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¥1,398.39

说明

一般描述

18-Crown-6 belongs to the class of Crown ethers, a group of macrocyclic polyethers, which have become valuable tools in organic synthesis, since they can solvate alkali, alkaline-earth and transition-metal cations in nonpolar, aprotic solvents. 18-Crown-6 is found to be most suitable for complexing with K+, NH4+ and Rb+ cations.
 

应用

18-Crown-6 may be used as a complexing agent, along with the mobile phase for the separation of alkali and alkaline earth metal and amine cations and its application for the direct analysis of ammonia from nitrogenase is studied.[1] It may also be used as a complexing agent in the determination of inorganic and organic anions, alkali, alkaline earth and transition metal cations by capillary electrophoresis using contactless conductometric detector.[2]
Learn more in the Product Information
有效用作相转移催化剂。
 

其他说明

具有重复 (-CH2CH2O) 单元的大环聚醚。该化合物为离子载体型(与阳离子形成稳定的复合物)。
 

联系

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Discover LiChropur reagents ideal for HPLC or LC-MS analysis
 

法律信息

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
 
 

属性

质量水平

测定

≥99.0% (GC)

形式

solid

technique(s)

ion chromatography: suitable

mp

42-45 °C (lit.)

痕量阳离子

Al: ≤1 mg/kg
Ba: ≤1 mg/kg
Bi: ≤1 mg/kg
Ca: ≤1 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤1 mg/kg
K: ≤20 mg/kg
Li: ≤1 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Mo: ≤1 mg/kg
NH4+: ≤10 mg/kg
Na: ≤20 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Sr: ≤1 mg/kg
Zn: ≤1 mg/kg

SMILES string

O1CCOCCOCCOCCOCCOCC1

InChI

1S/C12H24O6/c1-2-14-5-6-16-9-10-18-12-11-17-8-7-15-4-3-13-1/h1-12H2

InChI key

XEZNGIUYQVAUSS-UHFFFAOYSA-N

 

安全信息

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral

储存分类代码

11 - Combustible Solids

WGK

WGK 3

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 20 | 欧洲Eur. ≥ 16 | 東京Tokyo ≥ 5 | 香港与北京 ≥ 20
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