[1,1′-双(二苯基膦)二茂铁]二氯化钯(II),[1,1′-Bis(diphenylphosphino)ferrocene] dichloropalladium(II) [Pd(dppf)Cl2];Umicore

线性分子式: (C17H14P)2Fe · PdCl2 CAS号: 72287-26-4 分子量: 731.70 MDL编号: MFCD00015757
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 931217
CAS号: 72287-26-4
MDL号: MFCD00015757
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¥789.66

说明

应用

CX93 is a catalyst for C-C and C-N coupling reaction. Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:-
  • Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
  • Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
  • Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

储存及稳定性

Do not store above 25 °C (77 °F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.
 

法律信息

Product of Umicore

This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

Additional information available at www.pmc.umicore.com
 
 

属性

质量水平

形式

powder

mp

266-283 °C (lit.)

储存温度

2-8°C

SMILES string

[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2

InChI key

JCWIWBWXCVGEAN-UHFFFAOYSA-L

 

安全信息

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 50 | 欧洲Eur. ≥ 12 | 東京Tokyo ≥ 20 | 香港与北京 ≥ 50
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