(-)-β-蒎烯，(−)-β-Pinene；≥97%, FCC, FG

图片 (-)-β-蒎烯，(−)-β-Pinene；≥97%, FCC, FG
别名：(1S,5S)-2(10)-蒎烯；(1S,5S)-6,6-二甲基-2-亚甲基二环[3.1.1]庚烷；(1S)-(-)-β-蒎烯；(1S,5S)-2(10)-Pinene, (-)-beta-Pinene, (1S,5S)-6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane, (1S)-(−)-β-Pinene

Empirical Formula (Hill Notation): C10H16 CAS号: 18172-67-3 分子量: 136.23 FEMA编号: 2903 Beilstein: 2038282 EC 号: 242-060-2 欧洲委员会编号: 2114 MDL编号: MFCD00001345 PubChem化学物质编号: 24901386 Flavis编号: 1.003 NACRES: NA.21
制造商品牌: 西格玛 Sigma-Aldrich
货号（SKU）: W290300
CAS号: 18172-67-3
MDL号: MFCD00001345
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¥612.54

说明

(-)-β-蒎烯 ((1S)-(-)-β-蒎烯, (1S,5S)-2(10)-蒎烯, (1S,5S)-6,6-Dimethyl-2-methylenebicyclo[3.1 .1]庚烷）是一种萜烯。已经提出在钯催化剂存在下通过氢化将其转化为左旋α-蒎烯。在室内气溶胶室实验中，在存在中性或酸性硫酸盐颗粒的情况下，它通过气相臭氧分解提供有机硫酸盐。据报道，它与臭氧的反应会产生 CO2、HCHO 和 6,6-二甲基双环[3.1.1]庚烷-2-酮。

β-蒎烯是一种从彼得森鳄梨木中散发出来的挥发性单萜类化合物。据报道，使用主化学机制版本 3 (MCM v3) 从 α- 和 β- 蒎烯的气相臭氧分解产生二次有机气溶胶 (SOA)。 β-蒎烯是从 Cedronella canariensis 中分离出来的精油的关键成分。它也是黑松和松树树脂精油的主要成分。

(-)-β-蒎烯可用于制备α-松油醇。
β-蒎烯已用于通过质谱分析从红月桂和鳄梨木释放的香气化合物。

一般描述

(-)-β-Pinene ((1S)-(-)-β-Pinene, (1S,5S)-2(10)-Pinene, (1S,5S)-6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane) is a terpene. Its conversion to leveorotatory α-pinene by hydrogenation in the presence of palladium catalyst has been proposed. It affords organosulfates on gas-phase ozonolysis in the presence of neutral or acidic sulfate particles during indoor aerosol chamber experiments. Its reaction with ozone has been reported to afford CO2, HCHO, and 6,6-dimethylbicyclo[3.1.1]heptan-2-one.
β-pinene is a volatile monoterepenoid emitted from the Peterson avocado wood. Generation of secondary organic aerosol (SOA) from the gas phase ozonolysis of α- and β-pinene using the Master Chemical Mechanism version 3 (MCM v3) has been reported. β-Pinene is the key ingredient of the essential oil isolated from Cedronella canariensis. It is also the main component of the essential oils of resins of Pinus brutia and Pinus pinea.
 

应用

(−)-β-Pinene may be used in the preparation of α-terpineol.
β-pinene has been used for the analysis of aroma compounds released from redbay and avocado wood by mass chromatography.
 
 

属性

质量水平

400

生物来源

synthetic

等级

FG
Halal
Kosher

reg. compliance

EU Regulation 1334/2008 & 178/2002
FCC
FDA 21 CFR 172.515
FDA 21 CFR 175.300
FDA 21 CFR 175.320

蒸汽密度

4.7 (vs air)

蒸汽压

~2 mmHg ( 20 °C)

测定

≥97%

旋光性

[α]20/D -30 to -15°, neat

折射率

n20/D 1.478 (lit.)

bp

165-167 °C (lit.)

mp

−61 °C (lit.)

溶解性

95% ethanol: soluble 1ml/3ml, clear, colorless

密度

0.866 g/mL at 25 °C

文件

see Safety & Documentation for available documents

性状检查

woody; herbaceous; pine

application(s)

flavors and fragrances

食品过敏原

no known allergens

SMILES string

[H][C@]12CCC(=C)[C@]([H])(C1)C2(C)C

InChI

1S/C10H16/c1-7-4-5-8-6-9(7)10(8,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9-/m0/s1

InChI key

WTARULDDTDQWMU-IUCAKERBSA-N

 

安全信息

警示用语：

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1

储存分类代码

3 - Flammable liquids

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储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 30 | 欧洲Eur. ≥ 10 | 東京Tokyo ≥ 9 | 香港与北京 ≥ 30
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