高锰酸钾,Potassium permanganate;ACS reagent, ≥99.0%, low in mercury

Empirical Formula (Hill Notation): KMnO4 CAS号: 7722-64-7 分子量: 158.03 EC 号: 231-760-3 MDL编号: MFCD00011364 PubChem化学物质编号: 329755916 NACRES: NA.21
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 399124
CAS号: 7722-64-7
MDL号: MFCD00011364
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说明

一般描述

Potassium permanganate (PP, KMnO4) is a dark violet colored crystalline solid. It is a strong oxidizing agent used in the oxidation of a wide range of organic compounds.[1] PP is commonly used as a disinfectant to treat external infections in aquaculture.[2] Corncobs pretreated with alkaline potassium permanganate solution showed high carbohydrate recovery due to the increased enzymatic hydrolysis of lignocellulose.[3] The acidic potassium permanganate chemiluminescence detection has been employed for the detection of cannabinoids.[4]
 

应用

Potassium permanganate was used in the preparation of layered MnO2 which may be employed as cathodic material in lithium secondary batteries.[5]
It may be used as an oxidant in:
  • The reduction of polycyclic aromatic hydrocarbons found in coal tar pitches (CTPs).[6]
  • Oxidation of decabromodiphenyl ether in sulfuric acid medium.[7]
  • Oxidative cleavage of oximes to the corresponding carbonyl compounds potassium permanganate supported on kieselguhr.[8]
  • Oxidation of progestagens.[9]
适用于非均相氧化。
 
 

属性

等级

ACS reagent

质量水平

检测方案

≥99.0%

形式

solid

reaction suitability

reagent type: oxidant

杂质

≤0.005% N compounds
≤0.2% insolubles

pH值(酸碱度)

7.2-9.7 (20 °C, 20 g/L)

溶解性

water: soluble 63.8 g/L at 20 °C(lit.)
acetone: soluble(lit.)
methanol: soluble(lit.)

痕量阴离子

chloride, chlorate (as Cl-): ≤0.005%
sulfate (SO42-): ≤0.02%

痕量阳离子

Hg: ≤0.05 ppm

SMILES string

[K+].[O-][Mn](=O)(=O)=O

InChI

1S/K.Mn.4O/q+1;;;;;-1

InChI key

VZJVWSHVAAUDKD-UHFFFAOYSA-N

 

安全信息

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2 - Repr. 2 - Skin Corr. 1 - STOT RE 2 Inhalation

靶器官

Brain

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 3

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 30 | 欧洲Eur. ≥ 10 | 東京Tokyo ≥ 9 | 香港与北京 ≥ 30
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