硝酸铝九水合物,Aluminum nitrate nonahydrate;99.99% (trace metals basis)

九水硝酸铝;Aluminium nitrate;线性分子式: Al(NO3)3 · 9H2O CAS号: 7784-27-2 分子量: 375.13 MDL编号: MFCD00149132
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 930954
CAS号: 7784-27-2
MDL号: MFCD00149132
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¥1,850.56

说明

硝酸铝是一种白色至无色盐,通常作为结晶九水合物遇到。溶于水、甲醇、乙醇、乙二醇。像许多三价硝酸盐一样,硝酸铝九水合物具有较低的熔点温度和分解温度。硝酸铝九水合物在74°C熔化,在100°C以下分解,失去硝酸和水,三氧化二氮和氧气,形成氧化铝。
硝酸铝是通过硝酸与氢氧化铝反应合成的。

硝酸铝主要用于生产氧化铝和氟化铝的涂料。由于其溶解性、作为强氧化剂的活性以及低分解温度,硝酸铝是通过湿化学方法进行保形涂层的重要铝来源。例如,研究人员通过将LiCoO2纳米颗粒分散在硝酸铝水溶液中并在80°C的适度温度下添加氟化铵,将LiCoO2正极材料涂覆在AlF3中。

硝酸铝九水合物也常用作合成层状双氢氧化物(LDHs)的前体。LDHs可以很容易地剥离成纳米片,是用作催化剂载体的高表面积材料,正在研究用于去除水中的污染物。

我们的硝酸铝也可以用作金属氧化物的有效铝掺杂剂。在这些合成中,硝酸铝与其他金属硝酸盐溶解。材料通过溶胶-凝胶处理、共沉淀然后煅烧或直接水热反应进行反应。由于这些工艺与金属硝酸盐的反应温度低,产物通常是高表面积纳米颗粒。例如,研究人员使用硝酸钴和硝酸铝通过溶胶-凝胶方法生产了用于水氧化应用的掺杂铝尖晶石 Co3O4。

一般描述

Aluminum nitrate is a white-to-colorless salt, typically encountered as the crystalline nonahydrate. It is soluble in water, methanol, ethanol, and ethylene glycol. Like many trivalent nitrates, aluminum nitrate nonahydrate has a low melting temperature and decomposition temperature. Aluminum nitrate nonahydrate melts at 74 °C and decomposes at temperatures below 100 °C, by losing nitric acid and water, dinitrogen trioxide and oxygen gas, and forming aluminum oxide.
Aluminum nitrate is synthesized by reacting nitric acid with aluminum hydroxide.

应用

Aluminum nitrate is primarily used to produce coatings of alumina and aluminum fluoride. Because of its solubility, its activity as a strong oxidizing agent, and its low decomposition temperature, aluminum nitrate is a great source of aluminum for conformal coatings by wet chemistry methods. For example, researchers have coated LiCoO2 cathode materials in AlF3 by dispersing LiCoO2 nanoparticles in aqueous solutions of aluminum nitrate and adding ammonium fluoride at modest temperatures of 80 °C.[1]

Aluminum nitrate nonahydrate is also commonly used as a precursor in the synthesis of layered double hydroxides (LDHs). LDHs, which can easily be exfoliated into nanosheets, are high-surface area materials used as catalyst supports[2] and under investigation for removing pollutants from water.[3]

Our aluminum nitrate can also be used as an effective aluminum dopant for metal oxides. In these syntheses, aluminum nitrate is dissolved with other metal nitrates. The materials are either reacted by sol-gel processing, co-precipitation followed by calcination, or direct hydrothermal reactions. Because of the low reaction temperatures of these processes with metal nitrates, the products are often high-surface area nanoparticles. For example, researchers produced Al-doped spinel Co3O4 for water oxidation applications by sol-gel methods using cobalt nitrate and aluminum nitrate.[4]
 
 

属性

描述

(2.5 - 3.5 at 50 g/L at 25 °C)

质量水平

测定

99.99% (trace metals basis)

形式

powder

杂质

≤150 ppm (trace metals analysis)

mp

73 °C (lit.)

溶解性

acetone: soluble
alcohols: soluble
water: soluble (highly soluble)

密度

1.72 g/cm3

SMILES string

O.O.O.O.O.O.O.O.O.[Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Al.3NO3.9H2O/c;3*2-1(3)4;;;;;;;;;/h;;;;9*1H2/q+3;3*-1;;;;;;;;;

InChI key

SWCIQHXIXUMHKA-UHFFFAOYSA-N

 

安全信息

象形图

Corrosion

警示用语:

Danger

危险声明

预防措施声明

危险分类

Eye Dam. 1

储存分类代码

13 - Non Combustible Solids

WGK

WGK 1

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 50 | 欧洲Eur. ≥ 12 | 東京Tokyo ≥ 20 | 香港与北京 ≥ 50