氯化铋(III)，Bismuth(III) chloride；99.99% trace metals basis

图片 氯化铋(III)，Bismuth(III) chloride；99.99% trace metals basis
别名：氯化铋；三氯化铋；三氯铋；Bismuth trichloride；Trichlorobismuth； Empirical Formula (Hill Notation): BiCl3 CAS号: 7787-60-2 分子量: 315.34 EC 号: 232-123-2 MDL编号: MFCD00003461 PubChem化学物质编号: 24855360 NACRES: NA.23
制造商品牌: 西格玛 Sigma-Aldrich
货号（SKU）: 254142
CAS号: 7787-60-2
MDL号: MFCD00003461
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¥2,167.58

说明

一般描述

Bismuth(III) chloride is a Lewis acid catalyst and a common source of Bi3+ ions used in various organic transformations and synthesis of bismuth nanomaterials.[1] [2]
 

应用

Bismuth(III) chloride can be used:
  • As a precursor to prepare polyaniline and bismuth(III) telluride nanohybrids with high thermoelectric performance.[1]
  • As a starting material to synthesize visible light absorbing double perovskite semiconductors, such as Cs2AgBiBr6 and Cs2AgBiCl6, eco-friendly alternative to the lead halide perovskites.[3]
  • To form a protective layer on anode materials.[4]
It can also be used as an efficient catalyst for green synthesis of:
  • Chalcones by Claisen–Schmidt reaction under solvent-free conditions.[5]
  • One-pot three-component synthesis of Propargylamines.[2]
  • Coumarins via ultrasound‐assisted Pechmann condensation of phenols with β‐ketoesters.

 

属性

质量水平

100

检测方案

99.99% trace metals basis

形式

solid

reaction suitability

reagent type: catalyst
core: bismuth

杂质

≤150.0 ppm Trace Metal Analysis

bp

447 °C (lit.)

mp

230-232 °C (lit.)

SMILES string

Cl[Bi](Cl)Cl

InChI

1S/Bi.3ClH/h;3*1H/q+3;;;/p-3

InChI key

JHXKRIRFYBPWGE-UHFFFAOYSA-K

 

安全信息

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315 - H319

危险分类

Eye Irrit. 2 - Skin Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 2

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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储存温度 Storage temp.常温阴凉避光
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