柠檬酸铁,Ferric citrate;technical grade

别名:枸橼酸铁;柠檬酸铁(III);柠檬酸铁(III)水合物;柠檬酸三铁;Iron(III) citrate hydrate;Iron(III) citrate

Empirical Formula (Hill Notation): C6H5FeO7 CAS号: 3522-50-7 分子量: 244.94 EC 号: 222-536-6 MDL编号: MFCD00013098 PubChem化学物质编号: 57654187
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): F6129
CAS号: 3522-50-7
MDL号: MFCD00013098
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¥1,245.96

说明

柠檬酸铁(III)技术等级为棕色至深橙色粉末。它溶于水,但不溶于大多数有机物,包括乙醇。粉末对光敏感;与许多铁羧酸盐一样,蓝光光还原柠檬酸铁(III),形成Fe2+离子,同时氧化羧基生成二氧化碳。柠檬酸铁(III)在460°C时热分解为α-Fe2O3。
柠檬酸铁(III)是含铁化合物的合成前体。它通常用于通过水热法制备Fe3O4纳米粒子或Fe3O4纳米复合材料,以及通过热分解和溶胶-凝胶工艺制备Fe2O3材料。柠檬酸铁(III)因其在水中的高溶解度和低溶解度无机相而非常适合于溶胶-凝胶工艺。因此,柠檬酸铁(III)是合成锂离子电池阴极所研究的掺杂铁和含铁金属氧化物的重要前体。
它还可用于降解四环素,以处理污染的水。

一般描述

Iron(III) citrate technical grade is a brown to dark orangepowder. It is soluble in water, but insoluble in most organics includingalcohols. The powder is sensitive to light; like many iron carboxylates, bluelight photo-reduces iron(III) citrate, forming the Fe2+ ion andconcomitantly oxidizing the carboxyl group to yield carbon dioxide. Iron(III)citrate thermally decomposes to α-Fe2O3 at 460 °C.
 

应用

Iron(III) citrate is a synthetic precursor for iron-containing compounds. It is commonly used to prepare Fe3Onanoparticles or Fe3O4-nanocomposites by hydrothermal methods and Fe2O3 materials by thermal decomposition and sol-gel processing. Iron(III) citrate is well-suited to sol-gel processing because of its high solubility in water and low solubility inorganic phases. Consequently, iron(III) citrate is an important precursor in the synthesis of iron-doped and iron-containing metal oxides studied for lithium-ion battery cathodes.

It can also be used in the degradation of tetracycline for the treatment of polluted water.
 
 

属性

等级

technical grade

质量水平

200

测定

16.5-18.5% Fe basis (iodometric)

形式

powder

组成

Fe, 16.5-18.5%

technique(s)

cell culture | mammalian: suitable

application(s)

battery manufacturing

SMILES string

OC12CC(=O)O[Fe](OC(=O)C1)OC2=O

InChI

1S/C6H8O7.Fe/c7-3(8)1-6(13,5(11)12)2-4(9)10;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);/q;+3/p-3

InChI key

NPFOYSMITVOQOS-UHFFFAOYSA-K

 

安全信息

储存分类代码

11 - Combustible Solids

WGK

WGK 3

个人防护装备

Eyeshields, Gloves, type N95 (US)

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 50 | 欧洲Eur. ≥ 12 | 東京Tokyo ≥ 20 | 香港与北京 ≥ 50
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