五氯化钼，Molybdenum(V) chloride；anhydrous, powder, 99.99% trace metals basis (excluding W)

图片 五氯化钼，Molybdenum(V) chloride；anhydrous, powder, 99.99% trace metals basis (excluding W)
别名：五氯钼；氯化钼(V)；Molybdenum pentachloride；Pentachloromolybdenum

线性分子式: MoCl5 CAS号: 10241-05-1 分子量: 273.21 EC 号: 233-575-3 MDL编号: MFCD00003467 PubChem化学物质编号: 24883197 NACRES: NA.23
制造商品牌: 西格玛 Sigma-Aldrich
货号（SKU）: 642452
CAS号: 10241-05-1
MDL号: MFCD00003467
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说明

一般描述

Molybdenum(V) chloride, also called as molybdenum pentachloride is a Lewis acid with high oxidation potential. It is widely used as a catalyst in the field of organic synthesis and polymer chemistry. It is also used as a chemical vapor deposition precursor.[1] [2]
 

应用

Molybdenum(V) chloride can be used:
  • As a catalyst for amidation of secondary benzyl alcohols.[1]
  • As a precursor to fabricate MoS2 thin films by atomic layer deposition method.[3]
  • As a primary catalyst for coordination polymerization of butadiene.[2]
  • To fabricate superior anode materials for Na-ion and Li-ion batteries.[4]
  • As a dual-function redox mediator for Li–O2 batteries to overcome thehigh polarization and low energy density issues.[5]
 

属性

等级

anhydrous

蒸汽压

1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)

检测方案

99.99% trace metals basis (excluding W)

形式

powder

杂质

≤150.0 ppm Trace Metal Analysis

bp

268 °C (lit.)

mp

194 °C (lit.)

密度

2.928 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

Cl[Mo](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5

InChI key

GICWIDZXWJGTCI-UHFFFAOYSA-I

 

安全信息

象形图

CorrosionHealth hazard
GHS05,GHS08

警示用语：

Danger

危险声明

H314 - H351

危险分类

Carc. 2 - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

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