二苯基二硒醚,Diphenyl diselenide;purum, ≥97.0% (GC)

别名:二苯联硒;Phenyl diselenide; 线性分子式: C6H5SeSeC6H5 CAS号: 1666-13-3 分子量: 312.13 Beilstein: 2047179 EC 号: 216-780-2 MDL编号: MFCD00003001 PubChem化学物质编号: 329756289 NACRES: NA.22
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 42944
CAS号: 1666-13-3
MDL号: MFCD00003001
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说明

一般描述

Diphenyl diselenide (Ph2Se2) is an organoselenium compound. Its crystalline structure,[1] toxicokinetic properties,[2] antioxidant and anti-inflammatory activities have been investigated.[3] Its ability to reverse the oxidative brain damage and mitochondrial dysfunction induced by acetaminophen has been studied in mice.[4] It reacts with thallium (Tl) to form TI (SePh).[5] It participates in a four-component radical coupling to form substituted cyclopentanes.[6]
 

应用

Diphenyl diselenide (Ph2Se2) may be used in the following studies:
  • methoxyselenenylation of alkenes[7]
  • dihydroxylation of double bonds[8]
  • hydrothiolation of terminal alkynes[9]
It may be used in the synthesis of the following:
  • unsymmetrical diorganyl selenides[10]
  • 1-(phenylselenomethyl)vinyl selenides[11]
  • allylic phenyl selenides[12]

其他说明

引入苯硒基的试剂,用于消去和氧化反应,综述[13]
 
 

属性

等级

purum

质量水平

测定

≥97.0% (GC)

mp

59-61 °C (lit.)
60-63 °C

SMILES string

[Se]([Se]c1ccccc1)c2ccccc2

InChI

1S/C12H10Se2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H

InChI key

YWWZCHLUQSHMCL-UHFFFAOYSA-N

 

安全信息

警示用语:

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

储存分类代码

6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 50 | 欧洲Eur. ≥ 12 | 東京Tokyo ≥ 20 | 香港与北京 ≥ 50
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