溴化钾,Potassium bromide;anhydrous, powder, free-flowing, Redi-Dri™, 99.999% trace metals basis

别名: Bromure de potassium, Kalii bromidum, Kaliumbromid, NSC 77367 线性分子式: KBr CAS号: 7758-02-3 分子量: 119.00 MDL编号: MFCD00011358
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 931128
CAS号: 7758-02-3
MDL号: MFCD00011358
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说明

一般描述

Potassium bromide is a white salt that crystallizes in the cubic rock salt structure, like sodium chloride. KBr is hygroscopic, deliquescent, highly soluble in water, and soluble in some polar organic solvents like glycerol, ethylene glycol, liquid ammonia, and hot ethanol, but insoluble in acetone. When dissolved, KBr dissociates completely into its ions, making it a useful source of bromine ions in double displacement reactions or salt metathesis reactions. For example, this property was used in the production photographic films of silver bromide: KBr was reacted with silver nitrate to precipitate silver bromide, a salt that decomposes on exposure to light.
 

应用

Potassium bromide is widely used in optics because KBr has a low refractive index and a wide spectral range into the infrared with nearly no absorption. As a result, KBr is widely used as infrared optical windows, as infrared beamsplitters, and as substrates for interferometers. Commonly KBr is used in transmission infrared spectroscopy as a media for powder samples. The KBr and powder are ground together and pressed, using a die, into a thin disc under vacuum. The disc suspends the sample without contributing to the transmitted signal. Potassium bromide has also been used in synthesis, commonly as a source of bromide ions. For example, double displacement of KBr and bismuth nitrate yielded nanosheets of bismuth oxybromide.[1] [2] Solutions of KBr have also been found to be useful shape-control agents or crystal-habit modifiers in formation of metal nanocrystals, including palladium nanorods[3] and bimetallic platinum-paladium nanocrystals.[4] [5] KBr is a common source of bromide ions used as nucleophiles in organic chemistry.
可用于除去外周膜蛋白。
 

特点和优势

  • Longer shelf-life as a free-flowing powder without addition of anti-caking agents
  • Slower absorption of environmental moisture
  • Conveniently resealable storage container in contrast to ampule -Faster dissolution compared to clumped materials
  • No need to chip, chisel, or grind clumped salts
  • While the Redi-Dri packaging system does offer desiccating properties, opening and closing of the Redi-Dri bottle is still intended to occur under controlled atmosphere to maintain the highest quality of your MilliporeSigma product.

法律信息

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC
 
 

属性

等级

anhydrous

质量水平

蒸汽压

<0.01 mmHg ( 20 °C)
1 mmHg ( 795 °C)

产品线

Redi-Dri

检测方案

99.999% trace metals basis

形式

powder

质量

free-flowing

杂质

≤15.0 ppm (trace metals analysis)

mp

734 °C (lit.)

溶解性

H2O: soluble ((lit.))
acetone: insoluble ((lit.))
hot ethanol: slightly soluble ((lit.))

SMILES string

[K+].[Br-]

InChI

1S/BrH.K/h1H;/q;+1/p-1

InChI key

IOLCXVTUBQKXJR-UHFFFAOYSA-M

 

安全信息

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2

储存分类代码

13 - Non Combustible Solids

WGK

WGK 1

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 50 | 欧洲Eur. ≥ 12 | 東京Tokyo ≥ 20 | 香港与北京 ≥ 50
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