氯磷酸二苯酯,Diphenyl phosphoryl chloride [DCP];96%

别名:二苯基氯磷酸酯;二苯磷酰氯;Diphenyl chlorophosphate;Diphenyl phosphorochloridate

线性分子式: (C6H5O)2POCl CAS号: 2524-64-3 分子量: 268.63 Beilstein: 654130 EC 号: 219-759-6 MDL编号: MFCD00003030 PubChem化学物质编号: 24861235 NACRES: NA.22
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 344249
CAS号: 2524-64-3
MDL号: MFCD00003030
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¥485.90

说明

一般描述

Diphenyl phosphoryl chloride is a diaryl phosphoryl derivative. It is formed during the preparation of monophenyl phosphoryl chloride via reaction of phenol and phosphorus oxychloride.[1]
 

应用

Diphenyl phosphoryl chloride may be used:
  • in the preparation of guanosine-adenosine-5′,5′-triphosphate, guanosine-cytidine-5′,5′-triphosphate, guanosine-uridine-5′,5′-triphosphate, diguanosine-5′,5′-diphosphate and diguanosine-5′,5′-triphosphate[2]
  • as phosphorylating agent for the synthesis of 2-deoxy-D-galactose-3 and -6 phosphoric acids[3]
  • in the synthesis of diaryl phosphoryl derivatives of alkylene dithiophosphates[4]

 

属性

蒸汽压

10 mmHg ( 190 °C)

质量水平

检测方案

96%

形式

liquid

折射率

n20/D 1.55 (lit.)

bp

314-316 °C/272 mmHg (lit.)

密度

1.296 g/mL at 25 °C (lit.)

SMILES字符串

ClP(=O)(Oc1ccccc1)Oc2ccccc2

InChI

1S/C12H10ClO3P/c13-17(14,15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H

InChI key

BHIIGRBMZRSDRI-UHFFFAOYSA-N

 

安全信息

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

> 113 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 30 | 欧洲Eur. ≥ 10 | 東京Tokyo ≥ 9 | 香港与北京 ≥ 30
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