正庚烷,Heptane;suitable for HPLC, ≥96%

线性分子式: CH3(CH2)5CH3 CAS号: 142-82-5 分子量: 100.20 Beilstein: 1730763 EC 号: 205-563-8 MDL编号: MFCD00009544 PubChem化学物质编号: 329758614 NACRES: NA.06
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 592579
CAS号: 142-82-5
MDL号: MFCD00009544
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¥1,590.35

说明

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. Heptane is an environmentally preferable solvent and greener alternative to hexane for chromatographic purification and thus has been enhanced for "Safer Solvents and Auxiliaries". Click here for more information.
Tools and techniques for solvent selection: green solvent selection guides.

Heptane (n-Heptane) is a primary reference fuel (PRF) for the rating of octane numbers of fuels in internal combustion engines. Its cetane number has been reported to be 56. Mechanism and kinetic studies of its oxidation in flow reactors, shock tubes and rapid compression machines have been proposed.[1] Its thermal decomposition has been studied under different conditions of temperature and pressure.[2] Its oxidative dehydrogenation in the presence of magnesium oxide supported vanadium catalyst has been investigated.[3] Molybdenum phosphide supported on Hβ zeolite (MoP/Hβ) catalyzed hydroisomerization of n-heptane has been reported to be enhanced by doping with secondary metals (Cr, Ni or Ce).[4]
 

应用

Greener alternatives to Hexane in HPLC.
Heptane (n-heptane) may be used:
  • To compose the solvent mixtures for the purification of N-acylpyrrolidine derivatives of fatty acid methyl esters (FAMEs) by TLC (Thin Layer Chromatography).[5]
  • To generate chiral alcohols and heptanones, via whole cell double oxidation.[6]
  • As a solvent in the synthesis of isopropyl acetate, via esterification of acetic acid with isopropyl alcohol catalyzed by lipase immobilized on silica.[7]

特点和优势

Greener alternative for hexane
 

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属性

蒸汽密度

3.5 (vs air)

质量水平

蒸汽压

40 mmHg ( 20 °C)
83 mmHg ( 37.7 °C)

测定

≥96%

形式

liquid

自燃温度

433 °F

组成

n-heptane, 96%

expl. lim.

7 %

环保替代产品特性

Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.

technique(s)

HPLC: suitable

杂质

<0.02% water

蒸发残留物

<0.0003%

颜色

APHA: ≤10

折射率

n20/D 1.387 (lit.)

bp

98 °C (lit.)
98 °C

mp

−91 °C (lit.)

溶解性

acetone: miscible(lit.)
carbon tetrachloride: soluble(lit.)
ethanol: very soluble(lit.)
ethyl acetate: miscible(lit.)
water: insoluble(lit.)

密度

0.684 g/mL at 25 °C (lit.)

λmax

400 nm (2nd)
0.01 at 254 nm

吸光度

0.10 at 225 nm
0.40 at 210 nm
1.0 at 197 nm

application(s)

food and beverages

环保替代产品分类

SMILES string

CCCCCCC

InChI

1S/C7H16/c1-3-5-7-6-4-2/h3-7H2,1-2H3

InChI key

IMNFDUFMRHMDMM-UHFFFAOYSA-N

 

安全信息

警示用语:

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Central nervous system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(F)

24.8 °F

闪点(C)

-4 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 50 | 欧洲Eur. ≥ 12 | 東京Tokyo ≥ 20 | 香港与北京 ≥ 50
商品标签 [tags]