四氯乙烯,Tetrachloroethylene [PCE];ACS reagent, ≥99.0%

全氯乙烯;Perchloroethylene;线性分子式: CCl2=CCl2 CAS号: 127-18-4 分子量: 165.83 Beilstein: 1361721 EC 号: 204-825-9 MDL编号: MFCD00000834 PubChem化学物质编号: 329756502 NACRES: NA.04
制造商品牌: 西格玛 Sigma-Aldrich
货号(SKU): 443786
CAS号: 127-18-4
MDL号: MFCD00000834
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说明

一般描述

Tetrachloroethylene (perchloroethylene, PCE), is a chlorinated ethylene compound commonly used as a dry cleaning and degreasing solvent.[1] It shows IR transparency as it has no C–H bonds making it an ideal solvent for IR spectroscopy.[2][3] PCE is a man-made pollutant which is difficult to degrade.[4] It is a ground water contaminant[5] which has adverse effect on human health due to its potential toxicity and carcinogenicity.[6] Some of the methods proposed for its degradation are Fenton oxidation treatment,[7] reductive dehalogenation under methanogenic condition,[6] and reduction using zero valent metal ions.[5] One of the methods reported for its synthesis is by reacting ethylene dichloride and chlorine.[8]
 

应用

Tetrachloroethylene may be used as a film-forming electrolyte additive in the manufacture of lithium ion batteries.[9] It may also be used as an extractant for the estimation of oil and grease in water by Fourier transform infrared spectroscopy (FT-IR).[2]
 
 

属性

等级

ACS reagent

质量水平

蒸汽密度

5.83 (vs air)

蒸汽压

13 mmHg ( 20 °C)
19 mmHg ( 25 °C)

检测方案

≥99.0%

形式

liquid

technique(s)

FTIR: suitable

杂质

≤0.05% water

蒸发残留物

≤0.0005%

颜色

APHA: ≤10

折射率

n20/D 1.505 (lit.)

bp

121 °C (lit.)

mp

−22 °C (lit.)

溶解性

water: soluble 0.15 g/L at 25 °C

密度

1.623 g/mL at 25 °C (lit.)

SMILES string

Cl\C(Cl)=C(\Cl)Cl

InChI

1S/C2Cl4/c3-1(4)2(5)6

InChI key

CYTYCFOTNPOANT-UHFFFAOYSA-N

 

安全信息

警示用语:

Warning

危险分类

Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Central nervous system

储存分类代码

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

商品规格
属性名称属性值
储存温度 Storage temp.常温阴凉避光
全球实时库存 Availability √美国St. Louis ≥ 20 | 欧洲Eur. ≥ 16 | 東京Tokyo ≥ 5 | 香港与北京 ≥ 20
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